Synthesis and Reactivity of Zirconium and Hafnium Dihydroxophthalocyaninates
Chernii V, Tretyakova I, Selin R, Fedosova N, Kovalska V (2020)
Publication Type: Journal article
Publication year: 2020
Journal
Book Volume: 65
Pages Range: 1489-1493
Journal Issue: 10
DOI: 10.1134/S0036023620100046
Abstract
Abstract—: Two synthetic approaches for obtaining of zirconium and hafnium dihydroxophthalocyaninates (i.e. (a) that using the zirconium and hafnium alkoxides as the reactive precursors and (b) hydrolysis of zirconium and hafnium dichloridophthalocyaninates) were evaluated. Reactivity of zirconium and hafnium dihydroxophthalocyaninates in their exchange reactions with β-diketones and with decanoic acid was also studied; they were compared with those of zirconium and hafnium dichloridophthalocyaninates. The use of zirconium and hafnium dihydroxophthalocyaninates as the precursors in their reactions with acid-sensitive ligands, such as ketoesters, is found to be a more effective approach.
Involved external institutions
Vernadsky Institute of general and inorganic chemistry / Інститут загальної та неорганічної хімії імені В. I. Вернадського НАН України
Ukraine (UA)
National Academy of Sciences of Ukraine (NAN) / Національна академія наук України
Ukraine (UA)
Ukraine (UA)
National Academy of Sciences of Ukraine (NAN) / Національна академія наук України
Ukraine (UA)
How to cite
APA:
Chernii, V., Tretyakova, I., Selin, R., Fedosova, N., & Kovalska, V. (2020). Synthesis and Reactivity of Zirconium and Hafnium Dihydroxophthalocyaninates. Russian Journal of Inorganic Chemistry, 65(10), 1489-1493. https://doi.org/10.1134/S0036023620100046
MLA:
Chernii, V., et al. "Synthesis and Reactivity of Zirconium and Hafnium Dihydroxophthalocyaninates." Russian Journal of Inorganic Chemistry 65.10 (2020): 1489-1493.
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