Chemically Reversible CO2 Uptake by Dendrimer-Impregnated Metal-Organic Frameworks
Goncalves RB, Cuadrado Collados C, Malliakas CD, Wang Z, Thommes M, Snurr RQ, Hupp JT (2024)
Publication Language: English
Publication Type: Journal article
Publication year: 2024
Journal
Book Volume: 40
Pages Range: 9299-9309
Journal Issue: 17
DOI: 10.1021/acs.langmuir.4c00885
Abstract
Industrialization over the past two centuries has resulted in a continuous rise in global CO2 emissions. These emissions are changing ecosystems and livelihoods. Therefore, methods are needed to capture these emissions from point sources and possibly from our atmosphere. Though the amount of CO2 is rising, it is challenging to capture directly from air because its concentration in air is extremely low, 0.04%. In this study, amines installed inside metal-organic frameworks (MOFs) are investigated for the adsorption of CO2, including at low concentrations. The amines used are polyamidoamine dendrimers that contain many primary amines. Chemically reversible adsorption of CO2 via carbamate formation was observed, as was enhanced uptake of carbon dioxide, likely via dendrimer-amide-based physisorption. Limiting factors in this initial study are comparatively low dendrimer loadings and slow kinetics for carbon dioxide uptake and release, even at 80 °C.
Authors with CRIS profile
Carlos Cuadrado Collados
Lehrstuhl für Thermische Verfahrenstechnik
Matthias Thommes
Lehrstuhl für Thermische Verfahrenstechnik
Involved external institutions
United States (USA) (US)How to cite
APA:
Goncalves, R.B., Cuadrado Collados, C., Malliakas, C.D., Wang, Z., Thommes, M., Snurr, R.Q., & Hupp, J.T. (2024). Chemically Reversible CO2 Uptake by Dendrimer-Impregnated Metal-Organic Frameworks. Langmuir, 40(17), 9299-9309. https://doi.org/10.1021/acs.langmuir.4c00885
MLA:
Goncalves, Rebecca B., et al. "Chemically Reversible CO2 Uptake by Dendrimer-Impregnated Metal-Organic Frameworks." Langmuir 40.17 (2024): 9299-9309.
BibTeX: Download