Stroek W, Keilwerth M, Malaspina LA, Grabowsky S, Meyer K, Albrecht M (2023)
Publication Type: Journal article
Publication year: 2023
Catalytic C−N bond formation by direct activation of C−H bonds offers wide synthetic potential. En route to C−H amination, complexes with organic azides are critical precursors towards the reactive nitrene intermediate. Despite their relevance, α-N coordinated organoazide complexes are scarce in general, and elusive with iron, although iron complexes are by far the most active catalysts for C−H amination with organoazides. Herein, we report the synthesis of a stable iron α-N coordinated organoazide complex from [Fe(N(SiMe
APA:
Stroek, W., Keilwerth, M., Malaspina, L.A., Grabowsky, S., Meyer, K., & Albrecht, M. (2023). Deciphering Iron-Catalyzed C−H Amination with Organic Azides: N2 Cleavage from a Stable Organoazide Complex. Chemistry - A European Journal. https://doi.org/10.1002/chem.202303410
MLA:
Stroek, Wowa, et al. "Deciphering Iron-Catalyzed C−H Amination with Organic Azides: N2 Cleavage from a Stable Organoazide Complex." Chemistry - A European Journal (2023).
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