Connecting Ruthenium Photocatalysis to 1,2-Dioxetane-Mediated Chemiluminescence: a Versatile Combination for Optical Detection and Read-Out

Köckenberger J, Thurston R, Sauer C, Oppl J, Heinrich M (2023)

Publication Type: Journal article

Publication year: 2023

Journal

Angewandte Chemie International Edition Wiley

DOI: 10.1002/anie.202304474

Abstract

Optical storage and photon quantification systems based on sensitive photoreactions have numerous applications. Herein, we report a highly efficient photocatalytic reaction, in which ruthenium photoredox catalysis is combined with a 1,2-dioxetane from which chemiluminescence can be triggered. In this system, blue light irradiation as optical input enables a defined inverse correlation with base-triggered, blue light emission as optical output. Comparison of readout by ¹H NMR and chemiluminescence, relative to previous optical input, underlines the reliability and usefulness of the ruthenium-dioxetane system for optical storage, sensing and ruthenium detection.

Authors with CRIS profile

Johannes Köckenberger Lehrstuhl für Pharmazeutische Chemie Ryan Thurston Professur für Pharmazeutische Chemie Caroline Sauer Lehrstuhl für Pharmazeutische Chemie Markus Heinrich Professur für Pharmazeutische Chemie

How to cite

APA:

Köckenberger, J., Thurston, R., Sauer, C., Oppl, J., & Heinrich, M. (2023). Connecting Ruthenium Photocatalysis to 1,2-Dioxetane-Mediated Chemiluminescence: a Versatile Combination for Optical Detection and Read-Out. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202304474

MLA:

Köckenberger, Johannes, et al. "Connecting Ruthenium Photocatalysis to 1,2-Dioxetane-Mediated Chemiluminescence: a Versatile Combination for Optical Detection and Read-Out." Angewandte Chemie International Edition (2023).

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