Observation of Giant Infrared Circular Dichroism in Plasmonic 2D-Metamaterial Arrays

Knipper R, Mayerhoefer TG, Kopecky V, Huebner U, Popp J (2018)

Publication Type: Journal article

Publication year: 2018

Journal

ACS Photonics American Chemical Society

Book Volume: 5

Pages Range: 1176-1180

Journal Issue: 4

DOI: 10.1021/acsphotonics.7b01477

Abstract

We report the observation of an enormous circular dichroism (CD) response in broadband surface-enhanced infrared absorption sensing arrays. In our experiment, a 2D-metamaterial chiral cross-slit array adjusted for application in conventional measurement setups was used. The inherent chirality of the design results in a very strong CD absorbance of 0.83 at around 2.86 μm (3500 cm-1). This far surpasses our predictions based on the finite-difference time-domain simulations. This is probably the highest CD response ever reported for the mid-infrared region. Our observation was rigorously validated; thus most error sources were ruled out. Further, this Letter discusses our results in view of possible remaining artifacts that might have had an influence on our observations, as both chiral enantiomers and an achiral counterpart with similar structure were created and measured. A giant CD 2D-metamaterial might lead toward surface-enhanced vibrational circular dichroism spectroscopy, a field that is subject to lively discussions.

Involved external institutions

Univerzita Karlova v Praze / Charles University in Prague CZ Czech Republic (CZ) Leibniz-Institut für Photonische Technologien e.V. DE Germany (DE)

How to cite

APA:

Knipper, R., Mayerhoefer, T.G., Kopecky, V., Huebner, U., & Popp, J. (2018). Observation of Giant Infrared Circular Dichroism in Plasmonic 2D-Metamaterial Arrays. ACS Photonics, 5(4), 1176-1180. https://doi.org/10.1021/acsphotonics.7b01477

MLA:

Knipper, Richard, et al. "Observation of Giant Infrared Circular Dichroism in Plasmonic 2D-Metamaterial Arrays." ACS Photonics 5.4 (2018): 1176-1180.

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