Benndorf S, Hofmeister E, Waechtler M, Goerls H, Liebing P, Peneva K, Gräfe S, Kupfer S, Dietzek-Ivansic B, Weigand W (2022)
Publication Type: Journal article
Publication year: 2022
Book Volume: 2022
Article Number: e202100959
Journal Issue: 3
[FeFe] hydrogenase mimicking complexes containing N-substituted naphthalene monoimide (NMI) of peri-substituted dichalcogenides as bridging ligands have been prepared and characterized using different spectroscopic as well as by X-ray diffraction methods. The redox behaviour has been investigated by cyclic voltammetry, IR and UV-Vis spectroelectrochemistry (IR and UV-Vis SEC), electron paramagnetic resonance (EPR) spectroscopy and quantum chemical simulations. IR SEC and EPR experiments combined with DFT calculations revealed the non-innocent character of the NMI bridging ligands. EPR spectroscopy was applied to study the singly and doubly reduced state. Chemical reduction with one equivalent of Cp*
APA:
Benndorf, S., Hofmeister, E., Waechtler, M., Goerls, H., Liebing, P., Peneva, K.,... Weigand, W. (2022). Unravelling the Mystery: Enlightenment of the Uncommon Electrochemistry of Naphthalene Monoimide [FeFe] Hydrogenase Mimics. European Journal of Inorganic Chemistry, 2022(3). https://doi.org/10.1002/ejic.202100959
MLA:
Benndorf, Stefan, et al. "Unravelling the Mystery: Enlightenment of the Uncommon Electrochemistry of Naphthalene Monoimide [FeFe] Hydrogenase Mimics." European Journal of Inorganic Chemistry 2022.3 (2022).
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