Slow relaxation of magnetization in a {Fe6Dy} complex deriving from a family of highly symmetric metallacryptands

Athanasopoulou AA, Carrella LM, Rentschler E (2019)

Publication Type: Journal article

Publication year: 2019

Journal

Dalton Transactions Royal Society of Chemistry

Book Volume: 48

Pages Range: 4779-4783

Journal Issue: 15

DOI: 10.1039/c9dt00552h

Abstract

The synthesis and characterization of a new family of isostructural {Fe 6 Ln} complexes, (pipH) 3 {Fe 6 Ln(shiH) 3 (shi) 6 }·1.5 pip·xH 2 O (Ln = Gd (1), Dy (2), Tb (3) and Y (4), pip = piperidine, and shi 3- = salicylhydroxamic acid) is reported. The resulting compounds possess an exceptionally unique structure of a metallacrown-like motif while the overall complexes feature more the structure of metallacryptates. Magnetic studies are reported and reveal that the {Fe 6 Dy} analogue belongs to the single-molecule magnet (SMM) family.

Involved external institutions

Johannes Gutenberg-Universität Mainz (JGU) DE Germany (DE)

How to cite

APA:

Athanasopoulou, A.A., Carrella, L.M., & Rentschler, E. (2019). Slow relaxation of magnetization in a {Fe6Dy} complex deriving from a family of highly symmetric metallacryptands. Dalton Transactions, 48(15), 4779-4783. https://doi.org/10.1039/c9dt00552h

MLA:

Athanasopoulou, Angeliki A., Luca M. Carrella, and Eva Rentschler. "Slow relaxation of magnetization in a {Fe6Dy} complex deriving from a family of highly symmetric metallacryptands." Dalton Transactions 48.15 (2019): 4779-4783.

BibTeX: Download