Three Novel Thiazole-Arm Containing 1,3,4-Oxadiazole-Based [HS-HS] Fe(II) Dinuclear Complexes

Sundaresan S, Eppelsheimer J, Carrella LM, Rentschler E (2022)

Publication Type: Journal article

Publication year: 2022

Journal

Crystals MDPI

Book Volume: 12

Article Number: 404

Journal Issue: 3

DOI: 10.3390/cryst12030404

Abstract

Novel synthesis of 2,5-bis[(1,3-thiazol-2-ylmethyl)amino]methyl-1,3,4-oxadiazole (LThia-zole) is reported, along with the preparation of three new dinuclear Fe(II) complexes with different counterions [Fe^II 2(µ2-L^Thiazole)2 ](BF4)4·2CH3 CN (1), [Fe^II 2(µ2-L^Thiazole)2 ](ClO4)4 (2) and [Fe^II 2(µ2-L^Thiazole)2 ](CF3 SO3)4·2CH3 CN (3). The obtained complexes were characterized by single-crystal X-ray crystallography, SQUID magnetometry and IR spectroscopy. The structure of the crystalline material was determined at 120 K for 1 and 3. The magnetic properties of all three complexes (1–3) were measured between 2–300 K and clearly show that all three complexes stay in the high-spin state over the measured temperature range.

Involved external institutions

Johannes Gutenberg-Universität Mainz (JGU)

Germany (DE)

How to cite

APA:

Sundaresan, S., Eppelsheimer, J., Carrella, L.M., & Rentschler, E. (2022). Three Novel Thiazole-Arm Containing 1,3,4-Oxadiazole-Based [HS-HS] Fe(II) Dinuclear Complexes. Crystals, 12(3). https://doi.org/10.3390/cryst12030404

MLA:

Sundaresan, Sriram, et al. "Three Novel Thiazole-Arm Containing 1,3,4-Oxadiazole-Based [HS-HS] Fe(II) Dinuclear Complexes." Crystals 12.3 (2022).

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