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In situ monitoring of structural changes during the adsorption on flexible porous coordination polymers by X-ray powder diffraction: Instrumentation and experimental results

Bon V, Senkovska I, Wallacher D, Heerwig A, Klein N, Zizak I, Feyerherm R, Dudzik E, Kaskel S (2014)

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Publication Type: Journal article

Publication year: 2014

Journal

Book Volume: 188

Pages Range: 190-195

DOI: 10.1016/j.micromeso.2013.12.024

Abstract

A new instrumentation for in situ X-ray powder diffraction allows to follow structural changes in the crystal structure of flexible coordination polymers during adsorption and desorption of gases. The system is based on closed cycle He-cryostat that ensures the high temperature stability in the range of 5.5-450 K. The automated gas dosing system facilitates the physisorption measurements in the pressure range of 0.01-130 kPa. The system is implemented on KMC-2 and MAGS beamlines at Helmholtz Zentrum Berlin für Materialien und Energie. Using new instrumentation, the adsorption of CO2 and n-butane at 273 K on a flexible two-dimensional coordination polymer ELM-11 (ELM - Elastic Layer Material) was investigated. © 2014 Elsevier Inc. All rights reserved.

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How to cite

APA:

Bon, V., Senkovska, I., Wallacher, D., Heerwig, A., Klein, N., Zizak, I.,... Kaskel, S. (2014). In situ monitoring of structural changes during the adsorption on flexible porous coordination polymers by X-ray powder diffraction: Instrumentation and experimental results. Microporous and Mesoporous Materials, 188, 190-195. https://doi.org/10.1016/j.micromeso.2013.12.024

MLA:

Bon, Volodymyr, et al. "In situ monitoring of structural changes during the adsorption on flexible porous coordination polymers by X-ray powder diffraction: Instrumentation and experimental results." Microporous and Mesoporous Materials 188 (2014): 190-195.

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