Revisiting thiol-yne chemistry: Selective and efficient monoaddition for block and graft copolymer formation
Sprafke JK, Spruell JM, Mattson KM, Montarnal D, Mcgrath AJ, Poetzsch R, Miyajima D, Hu J, Latimer AA, Voit B, Aida T, Hawker CJ (2015)
Publication Type: Journal article
Publication year: 2015
Journal
Book Volume: 53
Pages Range: 319-326
Journal Issue: 2
DOI: 10.1002/pola.27345
Abstract
The untapped potential of radical thiol-yne mono-addition chemistry is exploited to overcome the known limitations of thiol-ene chemistry in polymer coupling and block copolymer formation. By careful choice of alkyne, the reaction can selectively lead to the mono-addition product with efficiencies surpassing those achieved by traditional thiol-ene chemistry. This improvement is illustrated by the nearly quantitative synthesis of a variety of diblock and graft copolymers.
Involved external institutions
University of California
United States (USA) (US)
University of Tokyo
Japan (JP)
Leibniz-Institut für Polymerforschung Dresden e. V.
Germany (DE)
United States (USA) (US)
University of Tokyo
Japan (JP)
Leibniz-Institut für Polymerforschung Dresden e. V.
Germany (DE)
How to cite
APA:
Sprafke, J.K., Spruell, J.M., Mattson, K.M., Montarnal, D., Mcgrath, A.J., Poetzsch, R.,... Hawker, C.J. (2015). Revisiting thiol-yne chemistry: Selective and efficient monoaddition for block and graft copolymer formation. Journal of Polymer Science Part A-Polymer Chemistry, 53(2), 319-326. https://dx.doi.org/10.1002/pola.27345
MLA:
Sprafke, Johannes K., et al. "Revisiting thiol-yne chemistry: Selective and efficient monoaddition for block and graft copolymer formation." Journal of Polymer Science Part A-Polymer Chemistry 53.2 (2015): 319-326.
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