+: A Binary Phosphorus-Selenium Cation

Feldmann KO, Wiegand T, Ren J, Eckert H, Breternitz J, Groh MF, Mueller U, Ruck M, Maryasin B, Ochsenfeld C, Schoen O, Karaghiosoff K, Weigand JJ (2015)

Publication Type: Journal article

Publication year: 2015

Journal

Chemistry - A European Journal Wiley

Book Volume: 21

Pages Range: 9697-9712

Journal Issue: 27

DOI: 10.1002/chem.201406476

Abstract

Although a fairly large number of binary group 15/16 element cations have been reported, no example involving phosphorus in combination with a group 16 element has been synthesized and characterized to date. In this contribution is reported the synthesis and structural characterization of the first example of such a cation, namely a nortricyclane-type [P3Se4]+. This cation has been independently discovered by three groups through three different synthetic routes, as described herein. The molecular and electronic structure of the [P3Se4]+ cage and its crystal properties in the solid state have been characterized comprehensively by using X-ray diffraction, Raman, and nuclear magnetic resonance spectroscopies, as well as quantum chemical calculations.

Involved external institutions

Technische Universität Dresden DE Germany (DE) Westfälische Wilhelms-Universität (WWU) Münster DE Germany (DE) Ludwig-Maximilians-Universität (LMU) DE Germany (DE)

How to cite

APA:

Feldmann, K.-O., Wiegand, T., Ren, J., Eckert, H., Breternitz, J., Groh, M.F.,... Weigand, J.J. (2015). +: A Binary Phosphorus-Selenium Cation. Chemistry - A European Journal, 21(27), 9697-9712. https://doi.org/10.1002/chem.201406476

MLA:

Feldmann, Kai-Oliver, et al. "+: A Binary Phosphorus-Selenium Cation." Chemistry - A European Journal 21.27 (2015): 9697-9712.

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