Mechanism that governs the electro-optic response of second-order nonlinear polymers on silicon substrates

Schulz KM, Prorok S, Jalas D, Marder SR, Luo J, Jen AKY, Zierold R, Nielsch K, Eich M (2015)


Publication Type: Journal article

Publication year: 2015

Journal

Book Volume: 5

Pages Range: 1653-1660

Journal Issue: 8

DOI: 10.1364/OME.5.001653

Abstract

We use a modified Teng-Man technique to investigate the poling induced electro-optic activity of chromophore-doped organic polymers poled on silicon substrate in a thin film sample configuration. We reveal a fundamental difference between the poling processes on silicon substrate and ITO substrate. The electro-optic activity for polymers poled on silicon substrate is reduced which we ascribe to space charge formation at the silicon - organic interface that distorts the field distribution in the polymer film during high field poling, and therefore limits the effective induced polar order. We demonstrate that the electro-optic activity on silicon substrate can be improved by inserting a 5 nm thin dielectric layer of Al2O3q between the silicon substrate and the polymer which reduces the leakthrough current during poling, thereby allowing for higher applicable poling voltages.

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How to cite

APA:

Schulz, K.M., Prorok, S., Jalas, D., Marder, S.R., Luo, J., Jen, A.K.-Y.,... Eich, M. (2015). Mechanism that governs the electro-optic response of second-order nonlinear polymers on silicon substrates. Optical Materials Express, 5(8), 1653-1660. https://dx.doi.org/10.1364/OME.5.001653

MLA:

Schulz, K. Marvin, et al. "Mechanism that governs the electro-optic response of second-order nonlinear polymers on silicon substrates." Optical Materials Express 5.8 (2015): 1653-1660.

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