Tolerance of Flexible MOFs toward Repeated Adsorption Stress
Bon V, Kavoosi N, Senkovska I, Kaskel S (2015)
Publication Type: Journal article
Publication year: 2015
Journal
Book Volume: 7
Pages Range: 22292-22300
Journal Issue: 40
Abstract
The adsorption/desorption cyclability of four flexible MOFs, namely, MIL-53(Al), ELM-11, DUT-8(Ni), and SNU-9, was studied at 298 K using n-butane as adsorptive. The detailed analysis of thermal response curves, physisorption isotherm data, powder X-ray diffraction patterns, as well as SEM images revealed the highly stable switching performance of MIL-53(Al) and ELM-11 materials during 100 adsorption/desorption cycles. In contrast, for DUT-8(Ni) and SNU-9, the multiple adsorption/desorption stress leads to the reduction of crystallite size, causing changes in the switching behavior in the initial 10 physisorption runs, and a characteristic shift of the "gate-opening" pressure to higher values is observed.
Involved external institutions
Germany (DE)How to cite
APA:
Bon, V., Kavoosi, N., Senkovska, I., & Kaskel, S. (2015). Tolerance of Flexible MOFs toward Repeated Adsorption Stress. ACS Applied Materials and Interfaces, 7(40), 22292-22300. https://doi.org/10.1021/acsami.5b05456
MLA:
Bon, Volodymyr, et al. "Tolerance of Flexible MOFs toward Repeated Adsorption Stress." ACS Applied Materials and Interfaces 7.40 (2015): 22292-22300.
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