Cross-linked polymer-derived B/N co-doped carbon materials with selective capture of CO2

Zhao W, Han S, Zhuang X, Zhang F, Mai Y, Feng X (2015)

Publication Type: Journal article

Publication year: 2015

Journal

Journal of Materials Chemistry A Royal Society of Chemistry

Book Volume: 3

Pages Range: 23352-23359

Journal Issue: 46

DOI: 10.1039/c5ta06702b

Abstract

A new series of B, N-containing cross-linked polymers (PPs-BN) were achieved via Sonogashira cross coupling. These polymers exhibit very high carbon yields of around 70-80% even at 800°C, which allow them to be efficiently converted to B/N co-doped porous carbons after pyrolysis at high temperature under an inert atmosphere. The materials have been fully characterized by Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analyses, nitrogen sorption measurements and X-ray photoelectron spectroscopy, revealing their high contents of boron and nitrogen up to ∼3.21% and ∼5.72%, respectively, as well as porous structures with the largest specific surface area of 291 m2 g-1. Their CO2 capacities reached 3.25 mmol g-1 at 273 K under 1 atm. In addition, the very high selectivity for CO2/CH4 with a ratio of more than 5:1 at 298 K renders them applicable for gas separation and purification.

Involved external institutions

Shanghai Jiao Tong University / 上海交通大学 CN China (CN) Shanghai Institute of Technology CN China (CN)

How to cite

APA:

Zhao, W., Han, S., Zhuang, X., Zhang, F., Mai, Y., & Feng, X. (2015). Cross-linked polymer-derived B/N co-doped carbon materials with selective capture of CO2. Journal of Materials Chemistry A, 3(46), 23352-23359. https://doi.org/10.1039/c5ta06702b

MLA:

Zhao, Wuxue, et al. "Cross-linked polymer-derived B/N co-doped carbon materials with selective capture of CO2." Journal of Materials Chemistry A 3.46 (2015): 23352-23359.

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