Binder-free activated graphene compact films for all-solid-state micro-supercapacitors with high areal and volumetric capacitances
Wu ZS, Yang S, Zhang L, Wagner JB, Feng X, Müllen K (2015)
Publication Type: Journal article
Publication year: 2015
Journal
Book Volume: 1
Pages Range: 119-126
DOI: 10.1016/j.ensm.2015.09.004
Abstract
Micro-supercapacitors (MSCs) hold great promise as highly competitive miniaturized power sources satisfying the increased demand in microelectronics; however, simultaneously achieving high areal and volumetric capacitances is still a great challenge. Here we demonstrated the designed construction of binder-free, electrically conductive, nanoporous activated graphene (AG) compact films for high-performance MSCs. The binder-free AG films are fabricated by alternating deposition of electrochemically exfoliated graphene (EG) and nanoporous AG with a high specific surface area of 2920 m2/g, and then dry transferring onto the target substrates with a high-pressure mechanical densification process. Remarkably, the resulting compressed AG films showed uniform morphology in lateral dimensions, high conductivity (60 S/cm), nanoporous feature (<10 nm), and high packing density (0.8 g/cm3). The all-solid-state MSCs (AG-MSCs) based on these AG films simultaneously delivered an unprecedented areal capacitance of 89.5 mF/cm2 and volumetric capacitance of 147 F/cm3 for MSCs at 10 mV/s. Moreover, the fabricated AG-MSCs could be operated at a large scan rate of 10,000 mV/s, and showed outstanding cycling stability (capacitance retention of >99.6% after 10,000 cycles). Our results suggested that AG-MSCs are competitive for prospective applications of miniaturized energy storage devices.
Involved external institutions
Max-Planck-Institut für Polymerforschung (MPI-P) / Max Planck Institute for Polymer Research
Germany (DE)
Technical University of Denmark / Danmarks Tekniske Universitet (DTU)
Denmark (DK)
Technische Universität Dresden
Germany (DE)
Germany (DE)
Technical University of Denmark / Danmarks Tekniske Universitet (DTU)
Denmark (DK)
Technische Universität Dresden
Germany (DE)
How to cite
APA:
Wu, Z.S., Yang, S., Zhang, L., Wagner, J.B., Feng, X., & Müllen, K. (2015). Binder-free activated graphene compact films for all-solid-state micro-supercapacitors with high areal and volumetric capacitances. Energy Storage Materials, 1, 119-126. https://doi.org/10.1016/j.ensm.2015.09.004
MLA:
Wu, Zhong Shuai, et al. "Binder-free activated graphene compact films for all-solid-state micro-supercapacitors with high areal and volumetric capacitances." Energy Storage Materials 1 (2015): 119-126.
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