Controlled Synthesis of N-Doped Carbon Nanospheres with Tailored Mesopores through Self-Assembly of Colloidal Silica

Wang G, Sun Y, Li D, Liang HW, Dong R, Feng X, Muellen K (2015)

Publication Type: Journal article

Publication year: 2015

Journal

Angewandte Chemie International Edition Wiley

Book Volume: 54

Pages Range: 15191-15196

Journal Issue: 50

DOI: 10.1002/anie.201507735

Abstract

Limited strategies have been established to prepare monodisperse mesoporous carbon nanospheres (MCNs) with tailored pore sizes. In this work, a method is reported to synthesize MCNs by combining polymerization of aniline with co-assembly of colloidal silica nanoparticles. The controlled self-assembly behavior of colloidal silica enables the formation of uniform composite nanospheres and convenient modulation over mesopores. After carbonization and removal of sacrificial templates, the resultant MCNs possess tunable mesopores (7-42 nm) and spherical diameters (90-300 nm), as well as high surface area (785-1117 m2 g-1), large pore volume (1.46-2.01 cm3 g-1) and abundant nitrogen moieties (5.54-8.73 at %). When serving as metal-free electrocatalysts for the oxygen reduction reaction (ORR), MCNs with an optimum pore size of 22 nm, compared to those with 7 and 42 nm, exhibit the best ORR performance in alkaline medium. N-doped mesoporous carbon nanospheres (N-MCNs): A highly controlled self-assembly method based on colloidal silica was developed for the facile synthesis of N-MCNs with desired porous and chemical features (tunable mesopore size, high surface area, and N-doping content), which can serve as high-performance electrocatalysts for oxygen reduction reaction.

Involved external institutions

Max-Planck-Institut für Polymerforschung (MPI-P) / Max Planck Institute for Polymer Research DE Germany (DE) Chinese Academy of Sciences (CAS) / 中国科学院 CN China (CN) Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Wang, G., Sun, Y., Li, D., Liang, H.-W., Dong, R., Feng, X., & Muellen, K. (2015). Controlled Synthesis of N-Doped Carbon Nanospheres with Tailored Mesopores through Self-Assembly of Colloidal Silica. Angewandte Chemie International Edition, 54(50), 15191-15196. https://doi.org/10.1002/anie.201507735

MLA:

Wang, Gang, et al. "Controlled Synthesis of N-Doped Carbon Nanospheres with Tailored Mesopores through Self-Assembly of Colloidal Silica." Angewandte Chemie International Edition 54.50 (2015): 15191-15196.

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