A novel ionomeric polyurethane elastomer based on ionic liquid as crosslinker

Behera PK, Usha KM, Guchhait PK, Jehnichen D, Das A, Voit B, Singha NK (2016)

Publication Type: Journal article

Publication year: 2016

Journal

RSC Advances Royal Society of Chemistry

Book Volume: 6

Pages Range: 99404-99413

Journal Issue: 101

DOI: 10.1039/c6ra21650a

Abstract

A novel ionic liquid crosslinked flexible polyurethane elastomer (PUIL) was successfully synthesized by a one-pot polymerization method. A variety of characterization methods was employed to study the properties of PUIL, and they were compared with those of a linear thermoplastic polyurethane elastomer (TPU) prepared using butanediol (BDO) as a chain extender. A reference chemically crosslinked polyurethane (PUTMP) was also synthesized by using trimethylolpropane (TMP) as a non-ionic crosslinker. FT-IR spectroscopy revealed that the hydrogen bonding interaction was significantly suppressed in the presence of ionic liquid crosslinker leading to a highly flexible but tough elastomer material. Differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) demonstrated the improved flexibility of PUIL, as the glass transition temperature (Tg) of PUIL was lower than that of TPU and PUTMP. At the same time, PUIL exhibited a significantly higher tensile strength as well as higher elongation at break, as compared to TPU and PUTMP prepared without ionic liquid crosslinker. In the SAXS profiles, both TPU and PUIL showed single and broad peak characteristics of non-uniform microphase-separated morphology, whereas no phase separation was found in PUTMP. Contact angle measurement showed that the polarity of PUIL is higher than TPU and PUTMP, but importantly, the presence of ionic liquid crosslinks improved the oil resistance property.

Involved external institutions

Indian Institute of Technology Bombay

India (IN) Vikram Sarabhai Space Centre (VSSC) / विक्रम साराभाई अंतरिक्ष केंद्र

India (IN) Leibniz-Institut für Polymerforschung Dresden e. V.

Germany (DE)

How to cite

APA:

Behera, P.K., Usha, K.M., Guchhait, P.K., Jehnichen, D., Das, A., Voit, B., & Singha, N.K. (2016). A novel ionomeric polyurethane elastomer based on ionic liquid as crosslinker. RSC Advances, 6(101), 99404-99413. https://dx.doi.org/10.1039/c6ra21650a

MLA:

Behera, Prasanta Kumar, et al. "A novel ionomeric polyurethane elastomer based on ionic liquid as crosslinker." RSC Advances 6.101 (2016): 99404-99413.

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