Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate))

Shekurov R, Miluykov V, Kataeva O, Krivolapov D, Sinyashin O, Gerasimova T, Katsyuba S, Kovalenko V, Krupskaya Y, Kataev V, Buechner B, Senkovska I, Kaskel S (2016)

Publication Type: Journal article

Publication year: 2016

Journal

Crystal Growth and Design American Chemical Society

Book Volume: 16

Pages Range: 5084-5090

Journal Issue: 9

DOI: 10.1021/acs.cgd.6b00681

Abstract

A flexible and hydrolytically stable metal-organic framework [Mn(H2O)2(Fc(PHOO)2)·2H2O]n has been synthesized using ferrocene-based ligand bearing phosphinic groups (Fc(PHOOH)2 = 1,1′-ferrocenediyl-bis(H-phosphinic acid)). In this compound manganese atoms are bound by phosphinate fragments to give infinite chains, and the latter are interconnected by ferrocene groups to form two-dimensional coordination polymer. The elimination of both coordinated and lattice water molecules during heating up to 150 °C produced the compound, which is nonporous for nitrogen, but can selectively adsorb water over methanol and other solvents at 298 K. The reversible structural transformation during adsorption/desorption of water is also reflected in a change of magnetic properties of the metal-organic framework.

Involved external institutions

Russian Academy of Sciences / Росси́йская акаде́мия нау́к (RAS) RU Russian Federation (RU) Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden e.V. (IFW) / Leibniz Institute for Solid State and Materials Research Dresden DE Germany (DE) Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Shekurov, R., Miluykov, V., Kataeva, O., Krivolapov, D., Sinyashin, O., Gerasimova, T.,... Kaskel, S. (2016). Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate)). Crystal Growth and Design, 16(9), 5084-5090. https://doi.org/10.1021/acs.cgd.6b00681

MLA:

Shekurov, Ruslan, et al. "Reversible Water-Induced Structural and Magnetic Transformations and Selective Water Adsorption Properties of Poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate))." Crystal Growth and Design 16.9 (2016): 5084-5090.

BibTeX: Download