Zhuang X, Zhao W, Zhang F, Cao Y, Liu F, Bia S, Feng X (2016)
Publication Type: Journal article
Publication year: 2016
Book Volume: 7
Pages Range: 4176-4181
Journal Issue: 25
DOI: 10.1039/c6py00561f
The synthesis of crystalline two-dimensional (2D) covalent organic frameworks (COFs) with fully unsaturated carbon-carbon backbones via a solution approach remains a great challenge. In this work, we report the first example of an olefin-linked 2D conjugated COF using a Knoevenagel polycondensation reaction of 1,4-phenylene diacetonitrile and three armed aromatic aldehyde. The resulting 2D poly(phenelyenevinylene) framework (2DPPV) possesses a sheet morphology, and a crystalline layered structure featuring a fully sp2-bonded carbon skeleton with pendant cyanide groups. Its unique alternating structure with a serrated configuration has been essentially evaluated using HR-TEM TEM analysis, nitrogen physisorption measurements, PXRD studies and theoretical simulations. Upon thermal and activation treatments, the as-prepared 2DPPV can be facilely converted into porous carbon nanosheets with large specific surface areas of up to 880 m2 g-1 which exhibit an excellent electrochemical performance as supercapacitor electrodes and electrocatalysts for the oxygen reduction reaction. This represents an economic non-template approach to 2D porous carbon materials for energy-related applications.
APA:
Zhuang, X., Zhao, W., Zhang, F., Cao, Y., Liu, F., Bia, S., & Feng, X. (2016). A two-dimensional conjugated polymer framework with fully sp2-bonded carbon skeleton. Polymer Chemistry, 7(25), 4176-4181. https://doi.org/10.1039/c6py00561f
MLA:
Zhuang, Xiaodong, et al. "A two-dimensional conjugated polymer framework with fully sp2-bonded carbon skeleton." Polymer Chemistry 7.25 (2016): 4176-4181.
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