Derivatizing Tribenzothiophene-Fused Hexa-peri-hexabenzocoronenes with Tunable Optoelectronic Properties

Liu Y, Marszalek T, Muellen K, Pisula W, Feng X (2016)

Publication Type: Journal article

Publication year: 2016

Journal

Chemistry - An Asian Journal Wiley

Book Volume: 11

Pages Range: 2107-2112

Journal Issue: 15

DOI: 10.1002/asia.201600753

Abstract

A series of trisbenzothieno[1,2:7,8:13,14]hexa-peri-hexabenzocoronenes were synthesized and characterized by a combination of NMR, 2D NMR, MALDI-TOF MS, UV/Vis absorption spectroscopy, and 2D-WAXS measurement. By structural modulation like decoration of electro-donating alkoxyl chain, and conversion from an electron-rich thiophene ring into an electron-poor thiophene-S,S-dioxide moiety, the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of the hexabenzocoronenes derivatives can be effectively tuned which is further verified by the DFT calculations and cyclic voltammetry.

Involved external institutions

Max-Planck-Institut für Polymerforschung (MPI-P) / Max Planck Institute for Polymer Research DE Germany (DE) Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Liu, Y., Marszalek, T., Muellen, K., Pisula, W., & Feng, X. (2016). Derivatizing Tribenzothiophene-Fused Hexa-peri-hexabenzocoronenes with Tunable Optoelectronic Properties. Chemistry - An Asian Journal, 11(15), 2107-2112. https://doi.org/10.1002/asia.201600753

MLA:

Liu, Yi, et al. "Derivatizing Tribenzothiophene-Fused Hexa-peri-hexabenzocoronenes with Tunable Optoelectronic Properties." Chemistry - An Asian Journal 11.15 (2016): 2107-2112.

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