Hg4O3[ReO4]2, Featuring a 2D Polycationic Framework [Hg4O3]2+with Tetrahedral Rhenate(VII) Anions Embedded

Prasad BE, Nuss J, Felser C, Jansen M (2016)

Publication Type: Journal article

Publication year: 2016

Journal

Zeitschrift für Anorganische und Allgemeine Chemie Wiley

Book Volume: 642

Pages Range: 1359-1363

Journal Issue: 23

DOI: 10.1002/zaac.201600343

Abstract

New Hg4O3[ReO4]2was obtained via low temperature synthesis, at 65–70 °C. The coarse crystalline, single phase product is pale yellow, starts to decompose at 540 °C and sublimes without leaving behind any solid residue at 685 °C in an argon atmosphere. Its crystal structure [P21/n (14), a = 7.0104(10), b = 12.5046(18), c = 12.1692(18) Å, β = 91.838(3)°, Z = 4] can be rationalized as a stuffed HgRe2sub lattice, adopting the MgZn2Laves phase arrangement. The resulting structure after inserting the oxygen atoms consists of heavily corrugated 2D polycationic Hg/O networks stacked along [001] with the tetrahedral oxorhenate(VII) anions accommodated in the folds of individual layers.

Involved external institutions

Max-Planck-Institut für Chemische Physik fester Stoffe (MPI CPfS) / Max Planck Institute for Chemical Physics of Solids DE Germany (DE) Max-Planck-Institut für Festkörperforschung DE Germany (DE)

How to cite

APA:

Prasad, B.E., Nuss, J., Felser, C., & Jansen, M. (2016). Hg4O3[ReO4]2, Featuring a 2D Polycationic Framework [Hg4O3]2+with Tetrahedral Rhenate(VII) Anions Embedded. Zeitschrift für Anorganische und Allgemeine Chemie, 642(23), 1359-1363. https://doi.org/10.1002/zaac.201600343

MLA:

Prasad, Beluvalli E., et al. "Hg4O3[ReO4]2, Featuring a 2D Polycationic Framework [Hg4O3]2+with Tetrahedral Rhenate(VII) Anions Embedded." Zeitschrift für Anorganische und Allgemeine Chemie 642.23 (2016): 1359-1363.

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