Amsharov K (2016)
Publication Type: Journal article
Publication year: 2016
Book Volume: 253
Pages Range: 2473-2477
Journal Issue: 12
We report on thermal C–F bond activation in fluoroarenes by various metal oxides leading to effective C–C bond formation via cyclodehydrofluorination. We demonstrate that the transformation of the precursor molecule to the respective model nanographene/nanoribbon can be realized rather effectively on various metal oxides. It is found that intramolecular Aryl–Aryl cyclization via cyclodehydrofluorination can be performed at relatively mild condition. Our finding opens up a venue toward rational synthesis of carbon-based nanomaterial by bottom-up strategy directly on insulating metal oxide surfaces.
APA:
Amsharov, K. (2016). Cyclodehydrofluorination of fluoroarenes on metal oxides: Toward bottom-up synthesis of carbon nanostructures on insulating surfaces. physica status solidi (b), 253(12), 2473-2477. https://doi.org/10.1002/pssb.201600211
MLA:
Amsharov, Konstantin. "Cyclodehydrofluorination of fluoroarenes on metal oxides: Toward bottom-up synthesis of carbon nanostructures on insulating surfaces." physica status solidi (b) 253.12 (2016): 2473-2477.
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