Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation
Halder A, Kandambeth S, Biswal BP, Kaur G, Roy NC, Addicoat M, Salunke JK, Banerjee S, Vanka K, Heine T, Verma S, Banerjee R (2016)
Publication Type: Journal article
Publication year: 2016
Journal
Book Volume: 55
Pages Range: 7806-7810
Journal Issue: 27
Abstract
Two new chemically stable triazine- and phenyl-core-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and 2,3-DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time-dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs.
Involved external institutions
National Chemical Laboratory (NCL)
India (IN)
Indian Institute of Technology Kanpur (IITK)
India (IN)
Indian Institute of Technology Bombay
India (IN)
Jacobs University Bremen gGmbH
Germany (DE)
India (IN)
Indian Institute of Technology Kanpur (IITK)
India (IN)
Indian Institute of Technology Bombay
India (IN)
Jacobs University Bremen gGmbH
Germany (DE)
How to cite
APA:
Halder, A., Kandambeth, S., Biswal, B.P., Kaur, G., Roy, N.C., Addicoat, M.,... Banerjee, R. (2016). Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation. Angewandte Chemie International Edition, 55(27), 7806-7810. https://doi.org/10.1002/anie.201600087
MLA:
Halder, Arjun, et al. "Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation." Angewandte Chemie International Edition 55.27 (2016): 7806-7810.
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