Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations

Lin ZG, Fan LY, Kondinski A, Vankova N, Heine T, Chen BK, Haider A, Wang B, Kortz U, Hu CW (2016)

Publication Type: Journal article

Publication year: 2016

Journal

Inorganic Chemistry American Chemical Society

Book Volume: 55

Pages Range: 7811-7813

Journal Issue: 16

DOI: 10.1021/acs.inorgchem.6b01005

Abstract

The chiral dodecanuclear palladium(II) thio cluster LaPd12(C3H5NO2S)3(C3H6NO2S)21 (1) was prepared by reacting l-cysteine (l-Cys) with PdCl2 and La2O3 in aqueous solution under carefully controlled conditions. Compound 1 was structurally characterized by single-crystal XRD, TGA, IR, UV-vis, 13C NMR, and CD spectroscopy. Insight into the dimerization process of 1 was obtained by ESI-MS and DFT calculations.

Involved external institutions

Beijing Institute of Technology (BIT) / 北京理工大学 CN China (CN) Jacobs University Bremen gGmbH DE Germany (DE)

How to cite

APA:

Lin, Z.-G., Fan, L.-Y., Kondinski, A., Vankova, N., Heine, T., Chen, B.-K.,... Hu, C.-W. (2016). Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations. Inorganic Chemistry, 55(16), 7811-7813. https://doi.org/10.1021/acs.inorgchem.6b01005

MLA:

Lin, Zheng-Guo, et al. "Chiral Dodecanuclear Palladium(II) Thio Cluster: Synthesis, Structure, and Formation Mechanism Explored by ESI-MS and DFT Calculations." Inorganic Chemistry 55.16 (2016): 7811-7813.

BibTeX: Download