Seki T, Yu X, Zhang P, Yu CC, Liu K, Gunkel L, Dong R, Nagata Y, Feng X, Bonn M (2021)
Publication Type: Journal article
Publication year: 2021
Book Volume: 7
Pages Range: 2758-2770
Journal Issue: 10
DOI: 10.1016/j.chempr.2021.07.016
Unlike in the bulk, the hydrogen bond network of water is interrupted at water interfaces, and thus chemical reaction occurs at the water interface in a different manner than in the bulk, owning to, e.g., the possibility of templating molecules. On-water chemistry has generated highly crystalline, functional 2D materials through surfactant-monolayer-assisted interfacial synthesis (SMAIS). Yet, the details of the on-water reaction mechanism have remained unresolved. Here, by tracking the quasi-2D polyaniline film generation process using in situ surface-specific vibrational technique, we clarify how the polymerization reaction occurs at the water surfaces during SMAIS. We identify an aniline derivative with a positively charged terminal =NH
APA:
Seki, T., Yu, X., Zhang, P., Yu, C.-C., Liu, K., Gunkel, L.,... Bonn, M. (2021). Real-time study of on-water chemistry: Surfactant monolayer-assisted growth of a crystalline quasi-2D polymer. Chem, 7(10), 2758-2770. https://doi.org/10.1016/j.chempr.2021.07.016
MLA:
Seki, Takakazu, et al. "Real-time study of on-water chemistry: Surfactant monolayer-assisted growth of a crystalline quasi-2D polymer." Chem 7.10 (2021): 2758-2770.
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