Mixed-Valence Compounds as Polarizing Agents for Overhauser Dynamic Nuclear Polarization in Solids**
Gurinov A, Sieland B, Kuzhelev A, Elgabarty H, Kühne TD, Prisner T, Paradies J, Baldus M, Ivanov KL, Pylaeva S (2021)
Publication Type: Journal article
Publication year: 2021
Journal
Book Volume: 60
Pages Range: 15371-15375
Journal Issue: 28
Abstract
Herein, we investigate a novel set of polarizing agents—mixed-valence compounds—by theoretical and experimental methods and demonstrate their performance in high-field dynamic nuclear polarization (DNP) NMR experiments in the solid state. Mixed-valence compounds constitute a group of molecules in which molecular mobility persists even in solids. Consequently, such polarizing agents can be used to perform Overhauser-DNP experiments in the solid state, with favorable conditions for dynamic nuclear polarization formation at ultra-high magnetic fields.
Involved external institutions
Universiteit Utrecht (UU) / Utrecht University
Netherlands (NL)
Universität Paderborn
Germany (DE)
Goethe-Universität Frankfurt am Main
Germany (DE)
Russian Academy of Sciences / Росси́йская акаде́мия нау́к (RAS)
Russian Federation (RU)
Netherlands (NL)
Universität Paderborn
Germany (DE)
Goethe-Universität Frankfurt am Main
Germany (DE)
Russian Academy of Sciences / Росси́йская акаде́мия нау́к (RAS)
Russian Federation (RU)
How to cite
APA:
Gurinov, A., Sieland, B., Kuzhelev, A., Elgabarty, H., Kühne, T.D., Prisner, T.,... Pylaeva, S. (2021). Mixed-Valence Compounds as Polarizing Agents for Overhauser Dynamic Nuclear Polarization in Solids**. Angewandte Chemie International Edition, 60(28), 15371-15375. https://doi.org/10.1002/anie.202103215
MLA:
Gurinov, Andrei, et al. "Mixed-Valence Compounds as Polarizing Agents for Overhauser Dynamic Nuclear Polarization in Solids**." Angewandte Chemie International Edition 60.28 (2021): 15371-15375.
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