Heske J, Walczak R, Epping JD, Youk S, Sahoo SK, Antonietti M, Kühne TD, Oschatz M (2021)
Publication Type: Journal article
Publication year: 2021
Book Volume: 9
Pages Range: 22563-22572
Journal Issue: 39
DOI: 10.1039/d1ta05122a
The interaction between water molecules and surfaces in porous systems is of huge importance in various fields including but not limited to catalysis, adsorption, and the storage or conversion of electrochemical energy. Hydrophilicity of usually non-polar carbon-based materials can be enhanced by the incorporation of heteroatoms like nitrogen but insights into the interaction mechanisms on a molecular level remain hardly achievable due to the lack of porous carbons with a defined and regular atomic construction and a suitable structure model for such substances. This makes theoretical calculations difficult. In order to illuminate the interactions between nitrogen-containing carbon surfaces and water molecules, water adsorption is studied in this work on a series of model materials with different pore structures and atomic construction. In particular, volumetric adsorption measurements and1H solid-state NMR spectroscopic investigations in combination with theoretical calculations on water in nitrogen-rich C
APA:
Heske, J., Walczak, R., Epping, J.D., Youk, S., Sahoo, S.K., Antonietti, M.,... Oschatz, M. (2021). When water becomes an integral part of carbon - combining theory and experiment to understand the zeolite-like water adsorption properties of porous C2N materials. Journal of Materials Chemistry A, 9(39), 22563-22572. https://doi.org/10.1039/d1ta05122a
MLA:
Heske, Julian, et al. "When water becomes an integral part of carbon - combining theory and experiment to understand the zeolite-like water adsorption properties of porous C2N materials." Journal of Materials Chemistry A 9.39 (2021): 22563-22572.
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