Upgrading Organic Compounds through the Coupling of Electrooxidation with Hydrogen Evolution

Chen G, Li X, Feng X (2022)

Publication Type: Journal article, Review article

Publication year: 2022

Journal

Angewandte Chemie International Edition Wiley

Book Volume: 61

Article Number: e202209014

Journal Issue: 42

DOI: 10.1002/anie.202209014

Abstract

The electrocatalytic splitting of water is recognized to be the most sustainable and clean technology for the production of hydrogen (H2). Unfortunately, the efficiency is seriously restricted by the sluggish kinetics of the oxygen evolution reaction (OER) at the anode. In contrast to the OER, the electrooxidation of organic compounds (EOO) is more thermodynamically and kinetically favorable. Thus, the coupling of the EOO and hydrogen evolution reaction (HER) has emerged as an alternative route, as it can greatly improve the catalytic efficiency for the production of H2. Simultaneously, value-added organic compounds can be generated on the anode through electrooxidation upgrading. In this Minireview, we highlight the latest progress and milestones in coupling the EOO with the HER. Emphasis is focused on the design of the anode catalyst, understanding the reaction mechanism, and the construction of the electrolyzer. Moreover, challenges and prospects are offered relating to the future development of this emerging technology.

Involved external institutions

Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Chen, G., Li, X., & Feng, X. (2022). Upgrading Organic Compounds through the Coupling of Electrooxidation with Hydrogen Evolution. Angewandte Chemie International Edition, 61(42). https://doi.org/10.1002/anie.202209014

MLA:

Chen, Guangbo, Xiaodong Li, and Xinliang Feng. "Upgrading Organic Compounds through the Coupling of Electrooxidation with Hydrogen Evolution." Angewandte Chemie International Edition 61.42 (2022).

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