Bioactive Ion-Based Switchable Supercapacitors
Li P, Braeuniger Y, Kunigkeit J, Zhou H, Vega MRO, Zhang E, Grothe J, Brunner E, Kaskel S (2022)
Publication Type: Journal article
Publication year: 2022
Journal
Book Volume: 61
Article Number: e202212250
Journal Issue: 50
Abstract
Switchable supercapacitors (SCs) enable a reversible electrically-driven uptake/release of bioactive ions by polarizing porous carbon electrodes. Herein we demonstrate the first example of a bioactive ion-based switchable supercapacitor. Based on choline chloride and porous carbons we unravel the mechanism of physisorption vs. electrosorption by nuclear magnetic resonance, Raman, and impedance spectroscopy. Weak physisorption facilitates electrically-driven electrolyte depletion enabling the controllable uptake/release of electrolyte ions. A new 4-terminal device is proposed, with a main capacitor and a detective capacitor for monitoring bioactive ion adsorption in situ. Ion-concentration control in printed choline-based switchable SCs realizes switching down to 8.3 % residual capacitance. The exploration of adsorption mechanisms in printable microdevices will open an avenue of manipulating bioactive ions for the application of drug delivery, neuromodulation, or neuromorphic devices.
Involved external institutions
Germany (DE)How to cite
APA:
Li, P., Braeuniger, Y., Kunigkeit, J., Zhou, H., Vega, M.R.O., Zhang, E.,... Kaskel, S. (2022). Bioactive Ion-Based Switchable Supercapacitors. Angewandte Chemie International Edition, 61(50). https://doi.org/10.1002/anie.202212250
MLA:
Li, Panlong, et al. "Bioactive Ion-Based Switchable Supercapacitors." Angewandte Chemie International Edition 61.50 (2022).
BibTeX: Download