Lu Y, Zhang Y, Yang CY, Revuelta S, Qi H, Huang C, Jin W, Li Z, Vega-Mayoral V, Liu Y, Huang X, Pohl D, Polozij M, Zhou S, Canovas E, Heine T, Fabiano S, Feng X, Dong R (2022)
Publication Type: Journal article
Publication year: 2022
Book Volume: 13
Article Number: 7240
Journal Issue: 1
DOI: 10.1038/s41467-022-34820-6
Two-dimensional conjugated metal-organic frameworks (2D c-MOFs) have attracted increasing interests for (opto)-electronics and spintronics. They generally consist of van der Waals stacked layers and exhibit layer-depended electronic properties. While considerable efforts have been made to regulate the charge transport within a layer, precise control of electronic coupling between layers has not yet been achieved. Herein, we report a strategy to precisely tune interlayer charge transport in 2D c-MOFs via side-chain induced control of the layer spacing. We design hexaiminotriindole ligands allowing programmed functionalization with tailored alkyl chains (HATI_CX, X = 1,3,4; X refers to the carbon numbers of the alkyl chains) for the synthesis of semiconducting Ni
APA:
Lu, Y., Zhang, Y., Yang, C.-Y., Revuelta, S., Qi, H., Huang, C.,... Dong, R. (2022). Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks. Nature Communications, 13(1). https://doi.org/10.1038/s41467-022-34820-6
MLA:
Lu, Yang, et al. "Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks." Nature Communications 13.1 (2022).
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