Mechanistic Insights into the Cycling Behavior of Sulfur Dry-Film Cathodes

Fiedler M, Cangaz S, Hippauf F, Doerfler S, Abendroth T, Althues H, Kaskel S (2023)

Publication Type: Journal article

Publication year: 2023

Journal

Advanced Sustainable Systems Wiley

DOI: 10.1002/adsu.202200439

Abstract

All-solid-state lithium–sulfur batteries (ASSB-LiS batteries) are considered among advanced candidates for next-generation energy storage systems, as they break with restrictions and limitations that liquid electrolytes impose on lithium-ion batteries and lithium-sulfur batteries (LiS-batteries), meaning enhanced safety and higher energy densities. However, investigations under realistic conditions on pouch cell level are challenging, as it is necessary to implement a scalable preparation method for sheet-type cathodes with high sulfur utilization and loading. In this study, a solvent-free process to prepare free-standing cathode sheets with low binder content down to 0.1 wt% PTFE is demonstrated. The contribution of binder and electrolyte on the conversion reaction of sulfur is discussed. Sheet-type cathodes reach nearly theoretical sulfur utilization of 1672 mAh gS−1 and outstanding reversible capacity retention with 72% of initial discharge capacity after 400 cycles by adapting cut-off voltages to the stability window of the electrolyte. Furthermore, an all-solid-state pouch cell is demonstrated using the dry-film cathode, which is successfully tested for 50 cycles at different C-rates. Thickness monitoring of the cell stack gives fundamental insights into the volume change and breathing behavior of both cathode and anode.

Involved external institutions

Fraunhofer-Institut für Werkstoff- und Strahltechnik (IWS) / Fraunhofer Institute for Material and Beam Technology DE Germany (DE) Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Fiedler, M., Cangaz, S., Hippauf, F., Doerfler, S., Abendroth, T., Althues, H., & Kaskel, S. (2023). Mechanistic Insights into the Cycling Behavior of Sulfur Dry-Film Cathodes. Advanced Sustainable Systems. https://doi.org/10.1002/adsu.202200439

MLA:

Fiedler, Magdalena, et al. "Mechanistic Insights into the Cycling Behavior of Sulfur Dry-Film Cathodes." Advanced Sustainable Systems (2023).

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