Catching metallic nitride endohedral fullerenes in organic and aqueous media

Strauß V, Radhakrishnan SG, Malig J, Jux N, Guldi DM (2016)

Publication Type: Journal article

Publication year: 2016

Journal

Book Volume: 20

Pages Range: 1025-1033

Journal Issue: 8-11

DOI: 10.1142/S1088424616500711

Abstract

Two bis-tetraphenylporphyrin tweezers-like conjugates bearing different linkers have been characterized by means of electrochemical and photophysical methods. The thrust of this work was the complexation of these bis-porphyrins with C60 and metallic nitride endohedral fullerenes (MNEF) like Sc3N@C80 in organic and in aqueus media - studied by a combination of steady-state and time-resolved spectroscopies. In the context of charge separation evidence for the formation of the 1a(•+)-Sc3N@C80 (•-) and 1c(•+)-Sc3N@C80(•-) charge separated states in organic and aqueous media, respectively, came from transient absorption spectroscopy. Multi-wavelength analyses afforded charge separated state lifetimes of around 400 ps.

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How to cite

APA:

Strauß, V., Radhakrishnan, S.G., Malig, J., Jux, N., & Guldi, D.M. (2016). Catching metallic nitride endohedral fullerenes in organic and aqueous media. Journal of Porphyrins and Phthalocyanines, 20(8-11), 1025-1033. https://doi.org/10.1142/S1088424616500711

MLA:

Strauß, Volker, et al. "Catching metallic nitride endohedral fullerenes in organic and aqueous media." Journal of Porphyrins and Phthalocyanines 20.8-11 (2016): 1025-1033.

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