Zakgeym D, Hofmann JD, Maurer LA, Auer F, Müller K, Wolf M, Wasserscheid P (2023)
Publication Type: Journal article
Publication year: 2023
DOI: 10.1039/d2se01750d
Storage in liquid organic hydrogen carriers (LOHCs) constitutes a safe and infrastructure-compatible way to transport and handle hydrogen. To date, widely studied LOHC-systems are often differentiated into nitrogen-containing systems, such as N-ethylcarbazole (H0-NEC)/perhydro-N-ethylcarbazole (H12-NEC), or heteroatom-free LOHC systems, such as toluene/methylcyclohexane, benzyltoluene (H0-BT)/perhydro-benzyltoluene (H12-BT) and dibenzyltoluene (H0-DBT)/perhydro-dibenzyltoluene (H18-DBT). In this contribution we introduce the oxygen-containing LOHC system benzophenone/dicyclohexylmethanol, a system that is characterized by an excellent hydrogen storage capacity of 7.19 mass% or 2252 W h L−1. We herein demonstrate that benzophenone (H0-BP) can be selectively and completely hydrogenated to dicyclohexylmethanol (H14-BP, perhydro-benzophenone) over Ru/Al
APA:
Zakgeym, D., Hofmann, J.D., Maurer, L.A., Auer, F., Müller, K., Wolf, M., & Wasserscheid, P. (2023). Better through oxygen functionality? The benzophenone/dicyclohexylmethanol LOHC-system. Sustainable Energy & Fuels. https://doi.org/10.1039/d2se01750d
MLA:
Zakgeym, Dina, et al. "Better through oxygen functionality? The benzophenone/dicyclohexylmethanol LOHC-system." Sustainable Energy & Fuels (2023).
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