Nondirected Pd-catalyzed aerobic C-H alkenylation of ruthenocene and ferrocene

Mueller S, Lee W, Song JY, Kang E, Joo JM (2022)

Publication Type: Journal article

Publication year: 2022

Journal

Chemical Communications Royal Society of Chemistry

DOI: 10.1039/d2cc04208h

Abstract

Pd-catalyzed alkenylations of metallocenes via C-H activation were developed using electronically tunable pyrazolonaphthyridine (PzNPy) ligands. Ferrocene was alkenylated using the most electron-deficient ligand in the series, whereas the less reactive ruthenocene needed balancing of the electrophilicity and stability of catalysts. Various alkenes were installed, allowing fine-tuning of redox potentials.

Involved external institutions

Pusan National University (PNU) KR Korea, Republic of (KR)

How to cite

APA:

Mueller, S., Lee, W., Song, J.Y., Kang, E., & Joo, J.M. (2022). Nondirected Pd-catalyzed aerobic C-H alkenylation of ruthenocene and ferrocene. Chemical Communications. https://dx.doi.org/10.1039/d2cc04208h

MLA:

Mueller, Sven, et al. "Nondirected Pd-catalyzed aerobic C-H alkenylation of ruthenocene and ferrocene." Chemical Communications (2022).

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