Heinze M, Starke S, Haendler M, Komber H, Drache M, Moszner N, Voit B, Pospiech D (2019)
Publication Type: Journal article
Publication year: 2019
Book Volume: 136
Article Number: 48256
Journal Issue: 48
DOI: 10.1002/app.48256
We demonstrate in this study that the combination of modern inline monitoring methods [here: inline nuclear magnetic resonance (NMR)] with simulations gains more exact and profound kinetic results than previously used methods like linearization without that combination. The 1H-NMR spectroscopic data (more than 100 data points) are used to construct the copolymerization diagram. The reactivity ratios are obtained applying the van Herks nonlinear least square method. The examination of the radical copolymerization of 2-hydroxyethyl methacrylate (HEMA) with (2-{[2-(ethoxycarbonyl)prop-2-en-1-yl]oxy}ethyl) phosphonic acid (ECPPA) as important adhesive monomer used in dentistry yields reactivity ratios of r
APA:
Heinze, M., Starke, S., Haendler, M., Komber, H., Drache, M., Moszner, N.,... Pospiech, D. (2019). Combination of nuclear magnetic resonance spectroscopy and nonlinear methods to analyze the copolymerization of phosphonic acid derivatives. Journal of Applied Polymer Science, 136(48). https://doi.org/10.1002/app.48256
MLA:
Heinze, Marcus, et al. "Combination of nuclear magnetic resonance spectroscopy and nonlinear methods to analyze the copolymerization of phosphonic acid derivatives." Journal of Applied Polymer Science 136.48 (2019).
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