Tuning nature and temperature of structural and magnetic phase transitions of Mn3Cu1−yMyN1−xCx (M=Ag, Ni)
Born NO, Caron L, Seeler E, Felser C (2019)
Publication Type: Journal article
Publication year: 2019
Journal
Book Volume: 793
Pages Range: 185-190
DOI: 10.1016/j.jallcom.2019.04.160
Abstract
Antiperovskite materials based on Mn3CuN with Cu partially replaced by Ag or Ni and simultaneous substitution of N by C were synthesized and their magneto-structural transition was studied. By replacing Cu partially with Ag or Ni, Curie temperatures increase, the magnetostructural transition becomes isosymmetric and presents a more second order character. Simultaneous replacement of N by C reverses this trend as the Curie temperature decreases with increasing Ag/Ni content while the structural transition remains non-isosymmetric. Additionally, moderate magnetocaloric effects with magnetic entropy changes around 6 J/Kkg in the range of 130–150 K at a 2 T field change are observed. Finally, the influence of the change in number of valence electrons and cell size by substitution on the transition is discussed.
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How to cite
APA:
Born, N.-O., Caron, L., Seeler, E., & Felser, C. (2019). Tuning nature and temperature of structural and magnetic phase transitions of Mn3Cu1−yMyN1−xCx (M=Ag, Ni). Journal of Alloys and Compounds, 793, 185-190. https://doi.org/10.1016/j.jallcom.2019.04.160
MLA:
Born, N-O, et al. "Tuning nature and temperature of structural and magnetic phase transitions of Mn3Cu1−yMyN1−xCx (M=Ag, Ni)." Journal of Alloys and Compounds 793 (2019): 185-190.
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