Optimization of catalytic active sites in non-collinear antiferromagnetic Mn3Pt bulk single-crystal

Li G, Yang Q, Manna K, Fu C, Deniz H, Jena J, Li F, Parkin S, Auffermann G, Sun Y, Felser C (2019)

Publication Type: Journal article

Publication year: 2019

Journal

Materials Today Physics Elsevier

Book Volume: 10

Article Number: 100137

DOI: 10.1016/j.mtphys.2019.100137

Abstract

Electrons in non-collinear antiferromagnets exhibit abundant transfer properties of interest to next-generation innovative devices. As two of the most important properties of electrons, both charge and spin must be simultaneously transferred. This will certainly influence many surface reaction processes like the hydrogen evolution reaction (HER). We grow a Mn3Pt bulk single-crystal that having a room-temperature long-range magnetic order at the Mn sites, which showed Pt-like activity and excellent stability as a catalyst for HER. Experiments and density-functional-theory calculations reveal that the electronic structure can be modified owing to the spin polarization of the Mn atoms. This further affects the adsorption energy of the reaction intermediate by tailoring the arrangement and filling of d-electrons. With this strategy, a similar Gibbs free energy for hydrogen adsorption was obtained between Mn–Mn hollow sites and Pt sites. In other words, more actives sites beyond Pt are created. This study paves the way for the design of high-efficiency electrocatalysts through the interplay between the spin states and the adsorption-desorption behaviors.

Involved external institutions

Max-Planck-Institut für Chemische Physik fester Stoffe (MPI CPfS) / Max Planck Institute for Chemical Physics of Solids DE Germany (DE) Max-Planck-Institut für Mikrostrukturphysik (MSP) / Max Planck Institute for Microstructure Physics DE Germany (DE)

How to cite

APA:

Li, G., Yang, Q., Manna, K., Fu, C., Deniz, H., Jena, J.,... Felser, C. (2019). Optimization of catalytic active sites in non-collinear antiferromagnetic Mn3Pt bulk single-crystal. Materials Today Physics, 10. https://doi.org/10.1016/j.mtphys.2019.100137

MLA:

Li, Guowei, et al. "Optimization of catalytic active sites in non-collinear antiferromagnetic Mn3Pt bulk single-crystal." Materials Today Physics 10 (2019).

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