Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization
Graetz S, Oltermann M, Troschke E, Paasch S, Krause S, Brunner E, Borchardt L (2018)
Publication Type: Journal article
Publication year: 2018
Journal
Book Volume: 6
Pages Range: 21901-21905
Journal Issue: 44
DOI: 10.1039/c8ta03684e
Abstract
This study elucidates a mechanochemical approach to synthesize a microporous thiophene polymer via oxidative polymerization. Utilizing a design of experiments approach we optimized the reaction conditions leading to complete conversion and a polymer with a surface area of up to 1850 m2 g−1-almost twice as high as the material prepared by solution-based polymerization. Thus, our approach presents a solvent free, quick and scalable alternative for the production of porous polymers.
Involved external institutions
Germany (DE)How to cite
APA:
Graetz, S., Oltermann, M., Troschke, E., Paasch, S., Krause, S., Brunner, E., & Borchardt, L. (2018). Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization. Journal of Materials Chemistry A, 6(44), 21901-21905. https://doi.org/10.1039/c8ta03684e
MLA:
Graetz, S., et al. "Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization." Journal of Materials Chemistry A 6.44 (2018): 21901-21905.
BibTeX: Download