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Towards Rational Synthesis of Non-IPR Fullerenes Via Tandem Cyclodehydrofluorination of Fluoroarene-Based Precursors

Amsharov K (2017)

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Publication Type: Journal article

Publication year: 2017

Journal

Book Volume: 254

Article Number: 1700170

Journal Issue: 11

DOI: 10.1002/pssb.201700170

Abstract

In this report the successful generation of the non-isolated pentagon rule (non-IPR) fullerene fragment via regioselective cyclodehydrofluorination of a specially designed precursor under laser ionization condition is presented. It is demonstrated that the transformation of the precursor molecule to the highly strained non-IPR bowl-shaped hydrocarbon can be achieved effectively at rather low laser fluences, despite the presence of fused pentagons in the structure. This finding opens up a venue towards the rational synthesis of individual isomers of non-IPR fullerenes and other related non-IPR architectures by the bottom-up strategy. The retrosynthetic analysis of fluoroarene-based precursor molecules for non-IPR fullerenes C36–C50 is discussed.

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How to cite

APA:

Amsharov, K. (2017). Towards Rational Synthesis of Non-IPR Fullerenes Via Tandem Cyclodehydrofluorination of Fluoroarene-Based Precursors. physica status solidi (b), 254(11). https://doi.org/10.1002/pssb.201700170

MLA:

Amsharov, Konstantin. "Towards Rational Synthesis of Non-IPR Fullerenes Via Tandem Cyclodehydrofluorination of Fluoroarene-Based Precursors." physica status solidi (b) 254.11 (2017).

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