A new zeolitic lithium aluminum imidazolate framework

Jiang G, Bon V, Xu F, Garai B, Zhang E, Senkovska I, Poetke S, Hippauf F, Hausdorf S, Paasch S, Brunner E, Wang H, Kaskel S (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Dalton Transactions Royal Society of Chemistry

Book Volume: 50

Pages Range: 7933-7937

Journal Issue: 23

DOI: 10.1039/d1dt01017d

Abstract

An aliovalent mixed-metal framework DUT-174 [LiAl(2-methylimidazolate)4]n, isostructural to ZIF-8, was synthesized from lithium aluminum hydride (LiAlH4) and 2-methylimidazole (2-mImH) through dehydrogenation. Lithium and aluminum cations acting as alternating framework nodes are coordinated tetrahedrally by (2-mIm)^-. DUT-174 has a high specific surface area of 1149 m²g⁻¹and CO2uptake of 11.57 mmol g⁻¹at 195 K.

Involved external institutions

Technische Universität Dresden

Germany (DE) Fraunhofer-Institut für Werkstoff- und Strahltechnik (IWS) / Fraunhofer Institute for Material and Beam Technology

Germany (DE) Northwestern Polytechnical University / 西北工业大学 (NPU/NWPU)

China (CN)

How to cite

APA:

Jiang, G., Bon, V., Xu, F., Garai, B., Zhang, E., Senkovska, I.,... Kaskel, S. (2021). A new zeolitic lithium aluminum imidazolate framework. Dalton Transactions, 50(23), 7933-7937. https://doi.org/10.1039/d1dt01017d

MLA:

Jiang, Guangshen, et al. "A new zeolitic lithium aluminum imidazolate framework." Dalton Transactions 50.23 (2021): 7933-7937.

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