New 1D chiral Zr-MOFs based on in situ imine linker formation as catalysts for asymmetric C–C coupling reactions

Nguyen KD, Ehrling S, Senkovska I, Bon V, Kaskel S (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Journal of Catalysis Elsevier

Book Volume: 386

Pages Range: 106-116

DOI: 10.1016/j.jcat.2020.03.034

Abstract

A novel chiral diimine Zr-MOF (DUT-136, DUT - Dresden University of Technology) is synthesized in a one-pot reaction from ZrCl4, 4-formylbenzoic acid, and (R,R)-1,2-diphenylethylenediamine as an enantiopure core. Inspired by the versatile chemistry of the C[dbnd]N bond, a variety of post-synthetic derivatizations were performed. Oxidation, reduction, and metalation effectively generated the chiral amide-, amine-, and Ni containing DUT-136 MOFs, respectively. The catalytic activity of these post-synthetically modified materials was systemically evaluated in a wide range of asymmetric organic transformations, including the Friedel-Crafts alkylation, Michael addition, aldol reaction, and the Ni-catalyzed C–C coupling.

Involved external institutions

Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Nguyen, K.D., Ehrling, S., Senkovska, I., Bon, V., & Kaskel, S. (2020). New 1D chiral Zr-MOFs based on in situ imine linker formation as catalysts for asymmetric C–C coupling reactions. Journal of Catalysis, 386, 106-116. https://doi.org/10.1016/j.jcat.2020.03.034

MLA:

Nguyen, Khoa D., et al. "New 1D chiral Zr-MOFs based on in situ imine linker formation as catalysts for asymmetric C–C coupling reactions." Journal of Catalysis 386 (2020): 106-116.

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