Synthesis and Structure of the Silver(I) Complexes [Ag2(C4H6O4N)NO3]·H2O and Ag6(C6H6O6N)2 for the Formulation of Silver Inks in Nanoimprint Lithography

Kintzel S, Eckhardt K, Getzschmann J, Bon V, Grothe J, Kaskel S (2020)

Publication Type: Journal article

Publication year: 2020

Journal

European Journal of Inorganic Chemistry Wiley-VCH Verlag

Book Volume: 2020

Pages Range: 3167-3173

Journal Issue: 33

DOI: 10.1002/ejic.202000359

Abstract

Two new carboxylate silver(I) complexes, namely [Ag2(C4H6O4N)]NO3·H2O or [Ag2(HIDA)]NO3·H2O with IDA = iminodiacetate (1) and Ag6(C6H6O6N)2 or Ag6(NTA)2 with NTA = nitrilotriacetate (2) are synthesized and characterized by X-ray powder diffraction, thermal analysis and infrared spectroscopy. Rietveld refinement reveals [Ag2(HIDA)]NO3·H2O to form a 2D coordination polymer while Ag6(NTA)2 forms a 3D network, both featuring short Ag(d10)–Ag(d10) contacts. The resulting complexes are suitable precursors for the printing of silver structures at low temperature, in particular for micro and submicrometer patterns obtained via nanoimprint lithography. The patterns reveal low specific resistivity (ρ ≈ 10–7 Ω m) and good transmittance (> 50 %) in the visible range enabling applications in optoelectronic devices.

Involved external institutions

Technische Universität Dresden DE Germany (DE) Infineon Technologies Dresden GmbH & Co. KG DE Germany (DE)

How to cite

APA:

Kintzel, S., Eckhardt, K., Getzschmann, J., Bon, V., Grothe, J., & Kaskel, S. (2020). Synthesis and Structure of the Silver(I) Complexes [Ag2(C4H6O4N)NO3]·H2O and Ag6(C6H6O6N)2 for the Formulation of Silver Inks in Nanoimprint Lithography. European Journal of Inorganic Chemistry, 2020(33), 3167-3173. https://doi.org/10.1002/ejic.202000359

MLA:

Kintzel, Susann, et al. "Synthesis and Structure of the Silver(I) Complexes [Ag2(C4H6O4N)NO3]·H2O and Ag6(C6H6O6N)2 for the Formulation of Silver Inks in Nanoimprint Lithography." European Journal of Inorganic Chemistry 2020.33 (2020): 3167-3173.

BibTeX: Download