Towards highly active and stable nickel-based metal-organic frameworks as ethylene oligomerization catalysts

Arrozi USF, Bon V, Kutzscher C, Senkovska I, Kaskel S (2019)

Publication Type: Journal article

Publication year: 2019

Journal

Dalton Transactions Royal Society of Chemistry

Book Volume: 48

Pages Range: 3415-3421

Journal Issue: 10

DOI: 10.1039/c8dt03866j

Abstract

Catalytic ethylene oligomerization proceeds under mild conditions with high activity using porous or non-porous nickel-based coordination polymers/metal-organic frameworks (MOFs) as catalysts. The role of MOFs as catalyst precursors and the crucial impact of metal coordination on the catalyst activity and leaching are elucidated by comparing MOFs constructed from different clusters and linkers. The stronger the coordination bond of organic linkers to the Ni center, the lower the catalytic activity of the MOF, as shown for CPO-27(Ni). The highest activity and stability were obtained with the [Ni 3 (ndc) 3 (DMF) 2 ((CH 3 ) 2 NH) 2 ] n catalyst.

Involved external institutions

Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Arrozi, U.S.F., Bon, V., Kutzscher, C., Senkovska, I., & Kaskel, S. (2019). Towards highly active and stable nickel-based metal-organic frameworks as ethylene oligomerization catalysts. Dalton Transactions, 48(10), 3415-3421. https://doi.org/10.1039/c8dt03866j

MLA:

Arrozi, Ubed S. F., et al. "Towards highly active and stable nickel-based metal-organic frameworks as ethylene oligomerization catalysts." Dalton Transactions 48.10 (2019): 3415-3421.

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