Roztocki K, Lupa M, Slawek A, Makowski W, Senkovska I, Kaskel S, Matoga D (2018)
Publication Type: Journal article
Publication year: 2018
Book Volume: 57
Pages Range: 3287-3296
Journal Issue: 6
DOI: 10.1021/acs.inorgchem.8b00078
A new microporous cadmium metal-organic framework was synthesized both mechanochemically and in solution by using a sulfonyl-functionalized dicarboxylate linker and an acylhydrazone colinker. The three-dimensional framework is highly stable upon heating to 300 °C as well as in aqueous solutions at elevated temperatures or acidic conditions. The thermally activated material exhibits steep water vapor uptake at low relative pressures at 298 K and excellent recyclability up to 260 °C as confirmed by both quasi-equilibrated temperature-programmed desorption and adsorption (QE-TPDA) method as well as adsorption isotherm measurements. Reversible isotherms and hysteretic isobars recorded for the desorption-adsorption cycles indicate the maximum uptake of 0.19 g/g (at 298 K, up to p/p
APA:
Roztocki, K., Lupa, M., Slawek, A., Makowski, W., Senkovska, I., Kaskel, S., & Matoga, D. (2018). Water-Stable Metal-Organic Framework with Three Hydrogen-Bond Acceptors: Versatile Theoretical and Experimental Insights into Adsorption Ability and Thermo-Hydrolytic Stability. Inorganic Chemistry, 57(6), 3287-3296. https://doi.org/10.1021/acs.inorgchem.8b00078
MLA:
Roztocki, Kornel, et al. "Water-Stable Metal-Organic Framework with Three Hydrogen-Bond Acceptors: Versatile Theoretical and Experimental Insights into Adsorption Ability and Thermo-Hydrolytic Stability." Inorganic Chemistry 57.6 (2018): 3287-3296.
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