Selzer C, Werner A, Kaskel S (2018)
Publication Type: Journal article
Publication year: 2018
Book Volume: 57
Pages Range: 6609-6617
Journal Issue: 19
Hierarchical zeolite ZSM-58 was synthesized via a bottom-up synthesis method using varying amounts of carbon nanotubes (CNTs) as mesopore-generating template. Resulting ZSM-58 samples were analyzed by X-ray powder diffraction, scanning electron microscopy and physisorption experiments with argon, propane and propene. The adsorption of a binary propane/propene mixture was determined by breakthrough experiments. Furthermore, thermal response measurements using InfraSORP technology were applied to investigate the kinetics of propene adsorption on microporous vs hierarchical ZSM-58 samples. The use of up to 5 wt % CNTs as secondary template in the synthesis gel results in formation of zeolite ZSM-58 with mesopore volumes up to 0.06 cm3 g-1, while maintaining a high degree of crystallinity as demonstrated via X-ray powder diffraction. A direct correlation between the relative mesopore volume (V
APA:
Selzer, C., Werner, A., & Kaskel, S. (2018). Selective Adsorption of Propene over Propane on Hierarchical Zeolite ZSM-58. Industrial & Engineering Chemistry Research, 57(19), 6609-6617. https://doi.org/10.1021/acs.iecr.8b00377
MLA:
Selzer, Carolin, Anja Werner, and Stefan Kaskel. "Selective Adsorption of Propene over Propane on Hierarchical Zeolite ZSM-58." Industrial & Engineering Chemistry Research 57.19 (2018): 6609-6617.
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