Crystal Engineering of Phenylenebis(azanetriyl))tetrabenzoate Based Metal-Organic Frameworks for Gas Storage Applications

Mueller P, Bon V, Senkovska I, Getzschmann J, Weiss MS, Kaskel S (2017)

Publication Type: Journal article

Publication year: 2017

Journal

Crystal Growth and Design American Chemical Society

Book Volume: 17

Pages Range: 3221-3228

Journal Issue: 6

DOI: 10.1021/acs.cgd.7b00184

Abstract

The metal-organic framework (MOF) Cu4(mpbatb)2 (mpbatb-4,4′,4″,4-(1,3-phenylenebis(azanetriyl))tetrabenzoate), also known as DUT-71 (DUT - Dresden University of Technology), was functionalized via postsynthetic cross-linking of the copper paddle wheels by linear salen derivatives and dabco (1,4-diazabicyclo[2.2.2]octane). This results in a series of porous MOFs, denoted as DUT-117(M) (M - Cu, Ni, Pd). Besides significant improvement of the framework robustness, the influence of the metal coordinated by the salen ligand on the gas adsorption capacity (hydrogen -196 °C, methane 25 °C, and carbon dioxide 25 °C) was investigated. In this series DUT-117(Ni) stands out as the best material for adsorptive methane storage with a high working capacity of 171 cm3·cm-3 between 5 and 65 bar.

Involved external institutions

Technische Universität Dresden DE Germany (DE) Helmholtz-Zentrum Berlin für Materialien und Energie (HZB) DE Germany (DE)

How to cite

APA:

Mueller, P., Bon, V., Senkovska, I., Getzschmann, J., Weiss, M.S., & Kaskel, S. (2017). Crystal Engineering of Phenylenebis(azanetriyl))tetrabenzoate Based Metal-Organic Frameworks for Gas Storage Applications. Crystal Growth and Design, 17(6), 3221-3228. https://doi.org/10.1021/acs.cgd.7b00184

MLA:

Mueller, Philipp, et al. "Crystal Engineering of Phenylenebis(azanetriyl))tetrabenzoate Based Metal-Organic Frameworks for Gas Storage Applications." Crystal Growth and Design 17.6 (2017): 3221-3228.

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