Synthesis and Properties of Acridine and Acridinium Dye Functionalized Bis(terpyridine) Ruthenium(II) Complexes

Eberhard J, Peuntinger K, Froehlich R, Guldi DM, Mattay J (2018)

Publication Type: Journal article

Publication year: 2018

Journal

European Journal of Organic Chemistry Wiley

Book Volume: 2018

Pages Range: 2682-2700

Journal Issue: 20

DOI: 10.1002/ejoc.201800257

Abstract

We present first principle studies on the rational design of an acridine/N-methylacridinium dye (Acr/MeAcr+) substituted terpyridine ligand to investigate if these chromophores can act as triplet-energy storage units in bis(terpyridine) ruthenium(II) complexes. We studied the influence of the dye form (Acr/MeAcr+) as well as the interconnecting linker unit (none, 4-phenyl, or 5-thien-2-yl) and investigated these aspects by steady-state/time-resolved spectroscopy, cyclic voltammetry, X-ray structure analysis, and DFT calculations.

Authors with CRIS profile

Katrin Peuntinger Lehrstuhl für Physikalische Chemie I Dirk Michael Guldi Lehrstuhl für Physikalische Chemie I

Involved external institutions

Universität Bielefeld DE Germany (DE) Westfälische Wilhelms-Universität (WWU) Münster DE Germany (DE)

How to cite

APA:

Eberhard, J., Peuntinger, K., Froehlich, R., Guldi, D.M., & Mattay, J. (2018). Synthesis and Properties of Acridine and Acridinium Dye Functionalized Bis(terpyridine) Ruthenium(II) Complexes. European Journal of Organic Chemistry, 2018(20), 2682-2700. https://doi.org/10.1002/ejoc.201800257

MLA:

Eberhard, Jens, et al. "Synthesis and Properties of Acridine and Acridinium Dye Functionalized Bis(terpyridine) Ruthenium(II) Complexes." European Journal of Organic Chemistry 2018.20 (2018): 2682-2700.

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