Tri- and hexaferrocenyl-substituted subphthalocyanines in the quest for the optimum electron donor-acceptor distances
Fernandez-Ariza J, Krick Calderon R, Perles J, Salome Rodriguez-Morgade M, Guldi DM, Torres T (2017)
Publication Type: Journal article
Publication year: 2017
Journal
Book Volume: 53
Pages Range: 8525-8528
Journal Issue: 61
DOI: 10.1039/c7cc04726f
Abstract
Three and six ferrocenyl subunits have been attached to the periphery of subphthalocyanines (SubPcs). Unlike axially coordinated ferrocenes, peripherally-bonded ferrocenes have an impact on the electronic features of SubPcs, which show a 44 to 70 nm red-shift of their Q-bands. The unusually deep and narrow ferrocenyl-SubPc is able to host C60, giving rise to atypical SubPc•C60 cocrystallates, through a combination of concave-convex and convex-convex π-π interactions.
Authors with CRIS profile
Rafael Krick Calderon
Lehrstuhl für Physikalische Chemie I
Dirk Michael Guldi
Lehrstuhl für Physikalische Chemie I
Involved external institutions
Spain (ES)How to cite
APA:
Fernandez-Ariza, J., Krick Calderon, R., Perles, J., Salome Rodriguez-Morgade, M., Guldi, D.M., & Torres, T. (2017). Tri- and hexaferrocenyl-substituted subphthalocyanines in the quest for the optimum electron donor-acceptor distances. Chemical Communications, 53(61), 8525-8528. https://doi.org/10.1039/c7cc04726f
MLA:
Fernandez-Ariza, Javier, et al. "Tri- and hexaferrocenyl-substituted subphthalocyanines in the quest for the optimum electron donor-acceptor distances." Chemical Communications 53.61 (2017): 8525-8528.
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