Charge Transport Layers Limiting the Efficiency of Perovskite Solar Cells: How To Optimize Conductivity, Doping, and Thickness

Le Corre VM, Stolterfoht M, Perdigón-Toro L, Feuerstein M, Wolff CM, Gil-Escrig L, Bolink HJ, Neher D, Koster LJA (2019)

Publication Status: Published

Publication Type: Journal article

Publication year: 2019

Journal

ACS Applied Energy Materials American Chemical Society

Publisher: AMER CHEMICAL SOC

Book Volume: 2

Pages Range: 6280-6287

Journal Issue: 9

DOI: 10.1021/acsaem.9b00856

Abstract

Perovskite solar cells (PSCs) are one of the main research topics of the photovoltaic community; with efficiencies now reaching up to 24%, PSCs are on the way to catching up with classical inorganic solar cells. However, PSCs have not yet reached their full potential. In fact, their efficiency is still limited by nonradiative recombination, mainly via trap-states and by losses due to the poor transport properties of the commonly used transport layers (TLs). Indeed, state-of-the-art TLs (especially if organic) suffer from rather low mobilities, typically within 10(-5) and 10(-2) cm(-2) V-1 s(-1), when compared to the high mobilities, 1-10 cm(-2) V-1 s(-1), measured for perovskites. This work presents a comprehensive analysis of the effect of the mobility, thickness, and doping density of the transport layers based on combined experimental and modeling results of two sets of devices made of a solution-processed high-performing triple-cation (PCE approximate to 20%). The results are also cross-checked on vacuum-processed MAPbI(3) devices. From this analysis, general guidelines on how to optimize a TL are introduced and especially a new and simple formula to easily calculate the amount of doping necessary to counterbalance the low mobility of the TLs.

Authors with CRIS profile

Vincent Marc Le Corre Institute Materials for Electronics and Energy Technology (i-MEET)

Involved external institutions

University of Groningen / Rijksuniversiteit Groningen NL Netherlands (NL) Universität Potsdam DE Germany (DE)

How to cite

APA:

Le Corre, V.M., Stolterfoht, M., Perdigón-Toro, L., Feuerstein, M., Wolff, C.M., Gil-Escrig, L.,... Koster, L.J.A. (2019). Charge Transport Layers Limiting the Efficiency of Perovskite Solar Cells: How To Optimize Conductivity, Doping, and Thickness. ACS Applied Energy Materials, 2(9), 6280-6287. https://doi.org/10.1021/acsaem.9b00856

MLA:

Le Corre, Vincent Marc, et al. "Charge Transport Layers Limiting the Efficiency of Perovskite Solar Cells: How To Optimize Conductivity, Doping, and Thickness." ACS Applied Energy Materials 2.9 (2019): 6280-6287.

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