Electrochemical- and mechanical stability of catalyst layers in anion exchange membrane water electrolysis

Mayerhöfer B, Speck FD, Hegelheimer M, Bierling M, Abbas D, McLaughlin D, Cherevko S, Thiele S, Peach R (2022)

Publication Type: Journal article

Publication year: 2022

Journal

International Journal of Hydrogen Energy Elsevier

Book Volume: 47

Pages Range: 4304-4314

Journal Issue: 7

DOI: 10.1016/j.ijhydene.2021.11.083

Abstract

Anion exchange membrane (AEM) water electrolysis is considered a promising solution to future cost reduction of electrochemically produced hydrogen. We present an AEM water electrolyzer with CuCoOx as the anode catalyst and Aemion as membrane and electrode binder. Full cell experiments in pure water and 0.1 M KOH revealed that the optimum binder content depended on the type of electrolyte employed. Online dissolution measurements suggested that Aemion alone was not sufficient to establish an alkaline environment for thermodynamically stabilizing the synthesized CuCoOx in a neutral electrolyte feed. A feed of base is thus indispensable to ensure the thermodynamic stability of such non-noble catalyst materials. Particle loss and delamination of the catalyst layer during MEA operation could be reduced by employing a heat treatment step after electrode fabrication. This work summarizes possible degradation pathways for low-cost anodes in AEMWE, and mitigation strategies for enhanced system durability and performance.

Authors with CRIS profile

Simon Thiele

Involved external institutions

Forschungszentrum Jülich / Research Centre Jülich (FZJ) DE Germany (DE)

How to cite

APA:

Mayerhöfer, B., Speck, F.D., Hegelheimer, M., Bierling, M., Abbas, D., McLaughlin, D.,... Peach, R. (2022). Electrochemical- and mechanical stability of catalyst layers in anion exchange membrane water electrolysis. International Journal of Hydrogen Energy, 47(7), 4304-4314. https://doi.org/10.1016/j.ijhydene.2021.11.083

MLA:

Mayerhöfer, Britta, et al. "Electrochemical- and mechanical stability of catalyst layers in anion exchange membrane water electrolysis." International Journal of Hydrogen Energy 47.7 (2022): 4304-4314.

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